1,4-Diazoniabicyclo[2.2.2]octane tetrachloridocadmate(II) monohydrate
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چکیده
The asymmetric unit of the title compound (C6H14N2)[CdCl4]·H2O contained one 1,4-di-aza-bicyclo-[2.2.2]octane dication, a tetrahedral CdCl4 (2-) anion and a lattice water mol-ecule. In the crystal, the solvate water mol-ecule inter-acts with the cationic and anionic species via N-H⋯O and O-H⋯Cl [O⋯Cl = 3.289 (7) Å] hydrogen-bond inter-actions, respectively, leading to a layered supramolecular structure extending parallel to (011).
منابع مشابه
Crystal structure of the new hybrid material bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridobismuthate(III)] dihydrate
The title compound bis-(1,4-diazo-niabi-cyclo-[2.2.2]octa-ne) di-μ-chlorido-bis-[tetra-chlorido-bis-muthate(III)] dihydrate, (C6H14N2)2[Bi2Cl10]·2H2O, was ob-tain-ed by slow evaporation at room temperature of a hydro-chloric aqueous solution (pH = 1) containing bis-muth(III) nitrate and 1,4-di-aza-bicyclo-[2.2.2]octane (DABCO) in a 1:2 molar ratio. The structure displays a two-dimensional arran...
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In the title compound, (C(6)H(14)N(2))[ZnCl(4)]·H(2)O, the crystal packing is governed by an extensive three-dimensional network of N-H⋯Cl, N-H⋯O and O-H⋯Cl hydrogen bonds. The zinc(II) metal centre has a slightly distorted tetra-hedral coordination geometry.
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1,4-diazoniabicyclo[2.2.2]octane diiodide monohydrate was synthesized by protonation of 1,4-diazabicyclo[2.2.2]octane (DABCO) with an excess of concentrated hydroiodic acid in water. It forms colourless rodlike crystals. At room temperature an orthorhombic unit cell, space group Cmc21, a 1⁄4 7.781(2) Å, b 1⁄4 13.010(3) Å, c 1⁄4 11.610(2) Å, V 1⁄4 1175.3(4) Å3, Z 1⁄4 4, is observed. Both nitroge...
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